【基本情况】
吴戟，男，1990年8月生，四川内江人，博士，讲师
主讲课程：高分子化学与物理，高分子材料改性
【研究方向】
过渡金属催化邻碳硼烷区域选择性B-H活化构建B-X（X=B，C，N，O）键
含碳硼烷固体荧光分子的合成及其光学性能的研究
含碳硼烷耐高温聚酰亚胺的合成与性能研究
【学习工作经历】
2021.06～至今，四川轻化工大学，讲师
2017.09～2021.06，西南科技大学，环境友好能源材料国家重点实验室；中国工程物理研究院，激光聚变研究中心，材料科学与工程专业，博士
2013.09～2017.06，西南科技大学，材料工程专业，硕士
2009.09～2013.06，西南科技大学，材料科学与工程专业，学士
【科研项目】
1.2017.01-2019.12，国家自然科学基金，基于钯催化亲电硼氢键活化的o-碳硼烷区域选择性单芳基化研究，主研，第二负责人；
2. 2018.01-2020.12，***靶制备技术，18zg8102, 国家级，主研，第三负责人;
3.2021.01-至今，国家自然科学基金，Pd/NHC催化o-碳硼烷(3,6)-H的选择性官能化及反应机理研究，主研，第三负责人。
【发表论文】
17. Ke Cao*, Ji Wu, Cai-Yan Zhang, Li-Fang Ding, Junxiao Yang, Iridium Catalyzed Selective Arylation of B(3)-H Bond of o-Carborane via B-H/C-H Activation, ChemistrySelect,2021, 6, 10178-10181.
16. Ke Cao*, Ji Wu, Cai-Yan Zhang, Li-Fang Ding, Junxiao Yang, Palladium catalyzed selective amination of B(7)-H for synthesis of o-carborane fused isoquinolinones, J. Organomet. Chem., 2021, 954-955, 122069.
15. Xin-Yu Wen,Ke Cao*,Ji Wu, Cai-Yan Zhang, Xia Li*, Linhai Jiang, Junxiao Yang, Free Radical Polymerization of o-Carborane Functionalized Styrene: Effect of Substitution Position at Carbon and Boron, ChemistrySelect,2021, 6, 4491-4494.
14. Ji Wu,Ke Cao*, Cai-Yan Zhang, Xin-Yu Wen, Bo Li*, Junxiao Yang, Iron(III)-catalyzed aerobic oxidation for the synthesis of 1-benzoxazolyl-o-carboranes, J. Organomet. Chem., 2021, 945, 121881.
13. Ke Cao*,Tao-Tao Xu, Ji Wu, Cai-Yan Zhang, Xin-Yu Wen, Junxiao Yang, The in Situ NHC-Palladium Catalyzed Selective Activation of B(3)-H or B(6)-H Bonds of o‐Carboranes for Hydroboration of Alkynes: An Efficient Approach to Alkenyl‐o‐carboranes, Inorg. Chem. 2021, 60, 1080-1085.
12. Ji Wu, Ke Cao*,Cai-Yan Zhang, Tao-Tao Xu, Xin-Yu Wen, Bo Li, Junxiao Yang, Palladium Catalyzed Selective B(3)-H Activation/Oxidative Dehydrogenative Coupling for the Synthesis of Bis(o‐carborane)s, Inorg. Chem.2020, 59, 17340-17346.
11. Ke Cao*, Cai-Yan Zhang, Tao-Tao Xu, Ji Wu, Xin-Yu Wen, Wen-Jun Jiang, Mao Chen, Junxiao Yang, Synthesis of Polyhedral Borane Cluster Fused Heterocycles via Transition Metal Catalyzed B-H Activation, Molecules,2020, 25, 391.
10. Tao-Tao Xu, Ke Cao*,Cai-Yan Zhang, Ji Wu, Li-Fang Ding, Junxiao Yang, Old Key Opens the Lock in Carborane: The in Situ NHC-Palladium Catalytic System for Selective Arylation of B(3,6)-H Bonds of o‐Carboranes via B-H Activation. Org. Lett. 2019, 21, 9276-9279.
9. Ke Cao*, Cai-Yan Zhang, Tao-Tao Xu, Ji Wu, Li-Fang Ding, Linhai Jiang, Junxiao Yang, Palladium catalyzed/counter ion tuned selective methylation of o-carboranes, J. Organomet. Chem.,2019, 902, 120956.
8. Ji Wu,Ke Cao*,Cai-Yan Zhang,Tao-Tao Xu,Li-Fang Ding,Bo Li,Junxiao Yang, Catalytic Oxidative Dehydrogenative Coupling of Cage B-H/B-H Bonds for Synthesis of Bis(o‐carborane)s, Org. Lett.2019, 21, 5986-5989.
7. Cai-Yan Zhang, Ke Cao*,Tao-Tao Xu, Ji Wu, Linhai Jiang*, Junxiao Yang, A facile approach for the synthesis of nido-carborane fused oxazoles via one pot deboronation/cyclization of 9-amide-o-carboranes, Chem. Commun., 2019, 55, 830-833.
6. Tao-Tao Xu,Ke Cao*, Cai-Yan Zhang,Ji Wu,Linhai Jiang, Junxiao Yang, Palladium catalyzed selective arylation of o-carboranes via B(4)-H activation: amide induced regioselectivity reversal, Chem.Commun.,2018,54,13603-13606.
5. Tao-Tao Xu, Ke Cao*,Ji Wu, Cai-Yan Zhang, Junxiao Yang, Palladium-Catalyzed Selective Mono-/Tetraacetoxylation of o‐Carboranes with Acetic Acid via Cross Dehydrogenative Coupling of Cage B-H/O-H Bonds, Inorg. Chem.,2018, 57, 2925-2932.
4. Tao-Tao Xu,Cai-Yan Zhang,Ke Cao*,Ji Wu,LinhaiJiang,*Jing Li,Bo Li,Junxiao Yang, Palladium-Catalyzed Selective Mono-Chlorination of o-Carboranes: Changing the Concept of FeCl3from Lewis Acid to Chlorine Source in Carboranes, ChemistrySelect,2017, 2, 3396-3399.
3.Ke Cao*, Tao-Tao Xu, Ji Wu, Linhai Jiang, Junxiao Yang. Palladium catalyzed/silver tuned selective mono-/ tetra-acetoxylation of o-carboranes via B-H activation, Chem. Commun., 2016, 52, 11446-11449.
2. Ji Wu, Ke Cao*,Tao-Tao Xu, Xiao-Juan Zhang, Linhai Jiang, Junxiao Yang, Yawen Huang. Palladium catalyzed regioselective mono- alkenylation of o-carboranes via Heck type coupling reaction of a cage B-H bond, RSC Adv., 2015, 5, 91683-91685.
1. Ke Cao*, Yawen Huang, Junxiao Yang, Ji Wu. Palladium catalyzed selective mono-arylation of o-carboranes via B-H activation. Chem. Commun., 2015, 51, 7257-7260.
【联系方式】
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